1. Tyrion Lannister from Game of Thrones. He is one my favorite characters (and I just watched season four of the show), and he is the best read and smartest one on the show.
2. Hermione Granger from The Harry Potter Series
3. Klaus from The Series of Unfortunate Events Series.
4. Charlie from The Perks of Being a Wallflower
5. Elizabeth from Pride and Prejudice
6. Matilda from Matilda
7. Vin from the Mistborn Series. She learns to read in the first novel, and spends a lot of time reading to try and save the kingdom, so it counts, lol.
8. Tuesday Next from the Eyre Affair
9. Joe from Little Women
10. Rory Gilmore! from Gilmore Girls. I'm rewatching the series from the boxset, on season five, loving it. :)